Advances in Sol-Gel Synthesis of MgZr4(1-x)Hf4xP6O24 (x = 0, 1) Solid Electrolytes for Electrochemical Devices
The potential solid electrolytes, MgZr4P6O24 and MgHf4P6O24 were prepared using modified novel sol-gel method. Structural and electrical properties of the solid electrolytes were determined. TGA-DSC analyses indicated that the pure dried xerogel powders, when calcined at 900 oC converts to pure single phase MgZr4P6O24 and MgHf4P6O24 nanopowders with excellent crystallinity. Pellets of 13 mm diamet...